Thermally conductive EMI shield

ABSTRACT

Electromagnetic-energy absorbing materials are combined with thermally conductive materials, such as those used for thermal management in association with electronic equipment, thereby suppressing the transmission of electromagnetic interference (EMI) therethrough. Disclosed are materials and processes for combining EMI-absorbing materials with thermally conductive materials thereby improving EMI shielding effectiveness in an economically efficient manner. In one embodiment, a thermally conductive EMI absorber is prepared by combining an EMI-absorbing material (for example, ferrite particles) with a thermally conducting material (for example, ceramic particles), each suspended within an elastomeric matrix (for example, silicone). In application, a layer of thermally conductive EMI-absorbing material is applied between an electronic device or component, and a heat sink

This patent application is a U.S. national stage filing under 35 U.S.C.§371 of International Application No. PCT/US2003/33353 filed Oct. 21,2003, which claims priority to U.S. provisional patent application No.60/419,873 filed Oct. 21, 2002.

BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention relates generally to thermal management inelectronic applications and, more specifically, to thermal conductorsincorporating electromagnetic-energy-attenuating properties.

2. Description of the Prior Art

As used herein, the term EMI should be considered to refer generally toboth electromagnetic interference and radio-frequency-interference (RFI)emissions, and the term “electromagnetic” should be considered to refergenerally to electromagnetic and radio frequency.

Electronic devices typically generate thermal emissions as anunavoidable byproduct. The amount of thermal emissions generated cancorrelate to the switching speed and complexity of the source electroniccomponent or device. As newer electronic devices tend to operate atgreater and greater switching speeds, they will also result in greaterthermal emissions. These increased thermal emissions, at some level,pose a risk of interfering with the function of the source electroniccomponent, and with the functions of other nearby devices andcomponents.

Accordingly, the unwanted thermal emissions should be dissipatedbenignly to preclude or minimize any undesirable effects. Prior-artsolutions addressing the removal of unwanted thermal emissions includeproviding a thermal pad over the electronic component and attaching aheat sink to the thermal pad. Heat sinks generally include material withhigh thermal conductivity. When placed in intimate contact with aheat-generating electronic component, the heat sink conducts thermalenergy away from the component. Heat sinks also include attributes thatfacilitate heat transfer from the heat sink to the ambient environment,for example, through convection. For example, heat sinks often include“fins” that result in a relatively large surface area for a givenvolume.

Furthermore, under normal operation, electronic equipment typicallygenerates undesirable electromagnetic energy that can interfere with theoperation of proximately located electronic equipment due to EMItransmission by radiation and conduction. The electromagnetic energy canexist over a wide range of wavelengths and frequencies. To minimizeproblems associated with EMI, sources of undesirable electromagneticenergy can be shielded and electrically grounded to reduce emissionsinto the surrounding environment. Alternatively, or additionally,susceptors of EMI can be similarly shielded and electrically grounded toprotect them from EMI within the surrounding environment. Accordingly,shielding is designed to prevent both ingress and egress ofelectromagnetic energy relative to a barrier, a housing, or otherenclosure in which the electronic equipment is disposed.

Sound EMI design principles recommend that EMI be treated as near aspossible to the source to preclude entry of unwanted EMI into the localenvironment, thereby minimizing the risk of interference. Unfortunately,components and devices requiring the use of heat sinks are not wellsuited for protective treatment for EMI at the source, because suchtreatment would interfere with the operation of the heat sink. The heatsink should be in intimate contact with the electronic component toprovide a thermal conduction path and also be open to the surroundingenvironment to allow for the heat sink to function through convectiveheat transfer.

SUMMARY OF THE INVENTION

In general, the present invention relates to anelectromagnetic-interference-absorbing thermally-conductive gap filler,such as an elastomeric (for example, silicone) pad treated with anelectromagnetic-interference-absorbing material. The EMI-absorbingmaterial absorbs a portion of the EMI incident upon the treated thermalpad, thereby reducing transmission of EMI therethrough over a range ofoperational frequencies. The absorbing material may remove a portion ofthe EMI from the environment through power dissipation resulting fromloss mechanisms. These loss mechanisms include polarization losses in adielectric material and conductive, or ohmic, losses in a conductivematerial having a finite conductivity.

Accordingly, in a first aspect, the invention relates to a compositematerial for reducing electromagnetic emissions generated by anelectronic device, the composite material including, in combination, athermally conductive material and an electromagnetic-energy-absorptivematerial. The thermally conductive material facilitates transfer ofthermal energy from the device and the electromagnetic-energy-absorptivematerial reduces electromagnetic emissions generated by the device.

In one embodiment, at least one of the thermally conductive material andthe electromagnetic-energy-absorptive material are granules. Thegranules may be generally spherical, such as microspheres, or othershapes, such as powder, fibers, flakes, and combinations thereof. Thecomposite further includes a matrix material in which the thermallyconductive material and the electromagnetic-energy-absorptive materialare suspended.

In general, the matrix material is substantially transparent toelectromagnetic energy, for example, being defined by a relativedielectric constant of less than approximately 4 and a loss tangent ofless than approximately 0.1. In one embodiment, the matrix is preparedas a liquid. In another embodiment, the matrix is prepared as a solid.In another embodiment, the-matrix is prepared as a phase-change materialexisting in a solid phase at ambient room temperature and transitioningto a liquid phase at equipment-operating temperatures. In anotherembodiment, the matrix is prepared as a thermosetting material.

In some embodiments, the thermally conductive EMI absorber is formed ina sheet having a thickness greater than approximately 0.010 inch andless than approximately 0.18 inch. In other embodiments, the sheetincludes a thermoconductive adhesive layer.

In another aspect, the invention relates to a method for reducingelectromagnetic emissions produced by a device, the method including thesteps of providing a thermally conductive material, providing anelectromagnetic-absorbing material, and combining the thermallyconductive material with the electromagnetic-absorbing material.

In one embodiment, the process includes the additional step ofsuspending the combined thermally conductive material andelectromagnetic-absorbing material in a matrix material.

In another embodiment, the process includes the additional step ofplacing the combined thermally conductive material andelectromagnetic-absorbing material between the device and proximatestructure, such as between an integrated circuit and a heat sink.

BRIEF DESCRIPTION OF THE DRAWINGS

The advantages of the invention may be better understood by referring tothe following description, taken in conjunction with the accompanyingdrawings, in which:

FIG. 1 is a schematic diagram depicting a perspective view of anembodiment of a thermally conductive EMI absorber identifying exemplaryconstituent components;

FIG. 2 is a schematic diagram depicting a perspective view of anexemplary application of a thermally conductive EMI absorber, such asthe embodiment illustrated in FIG. 1;

FIGS. 3A and 3B are schematic diagrams depicting perspective views ofalternative embodiments of a thermally conductive EMI absorber formed asa sheet and as a rollable tape, respectively;

FIG. 4 is a schematic diagram depicting an alternative embodiment of thethermally conductive EMI absorber depicted in FIG. 1, in which desiredshapes are cut, for example, from the sheet of FIG. 3A;

FIG. 5 is a schematic diagram depicting a perspective view of analternative embodiment of the thermally conductive EMI absorber depictedin FIG. 1, in which the shield is pre-formed according to apredetermined shape;

FIG. 6 is a schematic diagram of an alternative embodiment of athermally conductive EMI absorber in a flowable form, such as a liquid;

FIG. 7 is a schematic diagram depicting a perspective view of anexemplary application of a flowable, thermally conductive EMI absorber,such as the embodiment illustrated in FIG. 6;

FIG. 8 is a flow diagram depicting an embodiment of a process forpreparing a thermally conductive EMI absorber, such as the embodimentillustrated in FIG. 1; and

FIG. 9 is a schematic plan view of a test fixture used to measure thethermal conductivity of the thermally conductive EMI shield of thepresent invention.

DETAILED DESCRIPTION OF THE INVENTION

Materials having electromagnetic-energy absorbing properties can be usedto suppress the transmission of EMI over a broad range of frequencies.Such EMI-absorbing materials can provide substantialelectromagnetic-shielding effectiveness, for example, up to about 5 dBor more at EMI frequencies occurring from about 2 GHz up to about 100GHz.

According to the present invention, a thermally-conductive EMI absorbercan be formed by combining EMI-absorbing fillers and thermallyconducting fillers in a base matrix (for example, an elastomer) capableof being applied as a thermal gap filler, or pad. Generally, theresulting thermally-conductive EMI absorber can be applied as anythermal conductive material, for example, as between an electroniccomponent (e.g., a “chip”) and a heat sink.

Referring to FIG. 1, a thermally-conductive EMI absorber (thermal EMIshield) 100 is illustrated as a rectangular volume. The front face ofthe thermal EMI shield 100 represents a cross-sectional view of theinterior composition of the shield 100. Namely, the thermal EMI shield100 includes a number of EMI absorbers 110 and a number of thermalconductors 120, both being suspended within a matrix material 130.Although none of the EMI absorber particles 110 and the thermalconductor particles 120 are illustrated as being in contact with anyneighboring particles 110,120, configurations in which such contactoccurs are anticipated. For example, thermal conductivity of the thermalEMI shield 100 would generally be enhanced for configurations in whichthermal conductor particles 120 are in close proximity and contact witheach other.

The relative sizes of the individual EMI absorbers 110, thermalconductors 120, and the thickness of the matrix 130 as shown in FIG. 1are for illustration purposes only. In general, the suspended fillers110,120 are extremely small (that is, microscopic). Small fillerparticles 110,120 allow for embodiments in which the overall thicknessof the thermal EMI shield 100 is thin, for example, the thickness of thethermal EMI shield 100 is substantially less than the thickness ofeither the electronic component/device or the heat sink.

Similarly, the relative shapes of the suspended particles 110,120 can beany arbitrary shape. The elliptical shapes of the suspended particles110,120 shown in FIG. 1 are for illustration purposes only. In general,the shape of the suspended particles 110,120 can be granules, such asspheroids, ellipsoids, or irregular spheroids. Alternatively, the shapeof the suspended particles 110,120 can be strands, flakes, a powder, orcombinations of any or all of these shapes.

The EMI absorbers 110 function to absorb electromagnetic energy (thatis, EMI). Specifically, the EMI absorbers 110 convert electromagneticenergy into another form of energy through a process commonly referredto as a loss. Electrical loss mechanisms include conductivity losses,dielectric losses, and magnetization losses. Conductivity losses referto a reduction in EMI resulting from the conversion of electromagneticenergy into thermal energy. The electromagnetic energy induces currentsthat flow within an EMI absorber 110 having a finite conductivity. Thefinite conductivity results in a portion of the induced currentgenerating heat through a resistance. Dielectric losses refer to areduction in EMI resulting from the conversion of electromagnetic energyinto mechanical displacement of molecules within an absorber 110 havinga non-unitary relative dielectric constant. Magnetic losses refer to areduction in EMI resulting from the conversion of electromagnetic energyinto a realignment of magnetic moments within an EMI absorber 110.

In some embodiments, the EMI absorber 110 exhibits better thermalconductivity than air. For example, spherical iron particles selected asan EMI absorber 110 because of their EMI-absorbing properties also offersome level of thermal conductivity. Generally, however, the thermalconductivity of the EMI absorbers 110 of comparable thicknesses issubstantially less than the value of thermal conductivity offered bysubstantially non-EMI-absorbing thermal conductors 120, such as ceramicparticles.

In general, the EMI absorber 110 is selected from the group consistingof electrically conductive material, metallic silver, carbonyl ironpowder, SENDUST (an alloy containing 85% iron, 9.5% silicon and 5.5%aluminum), ferrites, iron silicide, magnetic alloys, magnetic flakes,and combinations thereof. In some embodiments, the EMI absorber 110 is amagnetic material. In one particular embodiment, the EMI absorber 110has a relative magnetic permeability greater than about 3.0 atapproximately 1.0 GHz, and greater than about 1.5 at 10 GHz.

The thermal conductor 120 includes a thermal impedance valuesubstantially less than that of air. A low value of thermal impedanceallows the thermal conductor 120 to efficiently conduct thermal energy.In general, the thermal conductor 120 is selected from the groupconsisting of aluminum nitride (AlN), boron nitride, iron (Fe), metallicoxides and combinations thereof. In some embodiments, the thermalconductor includes a ceramic material. In one particular embodiment, thethermal conductor 120 includes an Fe—AlN (40% and 20% by volume,respectively) having a thermal conductivity value greater than about 1.5Watts/m−° C. An exemplary test report including a test procedure formeasuring the thermal conductivity of a test sample, as well as measuredthermal conductivity test results, is provided herein as Appendix A andincorporated herein in its entirety.

In general, the matrix material 130 is selected to have propertiesallowing it to conform to surface imperfections encountered in manyheat-sink applications (for example, surface imperfections of the matingsurfaces of either the electronic component or device and the heatsink). Other desirable properties of the matrix material 130 include anability for the material 130 to accept and suspend a substantial volumeof particles 110,120, (for example, up to about 60% by volume) withoutcompromising the other advantageous properties of the matrix material130, such as conformability, compliance, and resilience. Generally, thematrix material 130 is also substantially transparent to electromagneticenergy so that the matrix material 130 does not impede the absorptiveaction of the EMI absorbers 110. For example, a matrix material 130exhibiting a relative dielectric constant of less than approximately 4and a loss tangent of less than approximately 0.1 is sufficientlytransparent to EMI. Values outside this range, however, are alsocontemplated.

Generally, the matrix material 130 can be selected as a solid, a liquid,or a phase-change material. Embodiments in which the matrix material 130is a solid further include thermoplastic materials and thermosetmaterials. Thermoplastic materials can be heated and formed, thenreheated and re-formed repeatedly. The shape of thermoplastic polymermolecules is generally linear, or slightly branched, allowing them toflow under pressure when heated above the effective melting point.Thermoset materials can also be heated and formed; however, they cannotbe reprocessed (that is, made to flow under pressure when reheated).Thermoset materials undergo a chemical as well as a phase change whenthey are heated. Their molecules form a three-dimensional cross-linkednetwork.

In some solid embodiments, the matrix material 130 is selected from thegroup consisting of elastomers, natural rubbers, synthetic rubbers, PDP,ethylene-propylene diene monomer (EPDM) rubber, and combinationsthereof. In other embodiments the matrix material 130 includes apolymer. The matrix material 130 can also be selected from the groupconsisting of silicone, fluorosilicone, isoprene, nitrile,chlorosulfonated polyethylene (for example, HYPALON®), neoprene,fluoroelastomer, urethane, thermoplastics, such as thermoplasticelastomer (TPE), polyamide TPE and thermoplastic polyurethane (TPU), andcombinations thereof.

Referring to FIG. 2, an exemplary application is illustrated in which anelectronic component 200, shown mounted on a circuit board 210, isfitted with a heat sink 220. The electronic component 200 can be anelectronic circuit (for example, a microcircuit, or “chip”).Alternatively, the electronic component 200 can be an electronic device,such as a packaged module including one or more electronic components(for example, mounted within a metallic housing, or “can”). In eitherinstance, the electronic component 200 creates, as a byproduct of itselectronic function, thermal energy that should be dissipated to ensurethat the electronic component 200 continues to operate within its designparameters and is protected from physical damage due to overheating.

In general, a heat sink 220 is a device for dissipating heat from a hostcomponent 200. The heat sink 220 first absorbs heat from the hostcomponent 200 through conduction. The heat sink 220 then dissipates theabsorbed heat through convection to the surrounding air. The particulartype or form of heat sink 220 selected is not critical. Rather, the heatsink 220 can be any one of a numerous variety of commercially availableheat sinks, or even a custom designed heat sink.

The thermal EMI shield 230 facilitates thermal conduction from thecomponent 200 to the heat sink 220. Generally, the thickness of thethermal EMI shield 230 (the dimension between the protected component200 and the heat sink) is less than a predetermined maximum value. Forexample, in one embodiment, the thermal EMI shield 230 has a maximumthickness less than approximately 0.18 inch. Furthermore, the thicknessof the thermal EMI shield 230 is generally greater than a predeterminedminimum value. If the thermal EMI shield is too thin, an insufficientvolume of EMI absorbing material will be provided to sufficiently absorbEMI from the component 200. For example, in one embodiment, the thermalEMI shield 230 has a minimum thickness greater than approximately 0.01inch.

In one exemplary configuration, a thermal EMI shield 230 having athickness of 0.125 inch, exhibits an attenuation of at least about 5 dBin a frequency range from about 5 GHz up to at least about 18 GHz. Inanother exemplary configuration, a thermal EMI shield 230 having athickness of 0.02 inch, exhibits an attenuation of at least about 3 dBfor a frequency range extending upward from about 10 GHz. In anotherexemplary configuration, a thermal EMI shield 230 having a thickness of0.04 inch, exhibits an attenuation of at least about 10 dB in afrequency range from about 9 GHz up to at least about 15 GHz and anattenuation of at least about 6 dB in a frequency range extending upwardfrom about 15 GHz. In yet another exemplary configuration, a thermal EMIshield 230 having a thickness of 0.060 inch, ±0.005 inch, exhibits anattenuation of at least about 5 dB in a frequency range extending upwardfrom about 4 GHz, having a greater attenuation of at least about 10 dBin a frequency range from about 6 GHz up to at least about 10 GHz.Exemplary values of the complex (real and imaginary) relativepermittivity (∈_(r)) and complex (real and imaginary) relative magneticpermeability (μ_(r)) for a nitrile rubber compound are tabulated andprovided herein as Appendix B, incorporated herein in its entirety.

Referring to FIG. 3A, a thermal EMI shield is illustrated in a sheetconfiguration. Generally, the thermal EMI shield can be formed as asheet 300. The sheet 300 includes a length (L′) a width (W′) and athickness (T′). In one embodiment, the length and width may be selectedaccording to the dimensions of a particular application, such as thelength and width of an electronic component 200 to which a heat sink 220will be applied. In another embodiment, the sheet 300 can be fabricatedin a predetermined size, such as a length of 26 inches, a width of 6inches, and a thickness of either 0.030 inch or 0.060 inch. Any size,however, is contemplated.

Yet other embodiments of a thermal EMI shield 100 may include a sheet300 as just described, further including an adhesive layer 310. Theadhesive layer 310 a may be a thermoconductive adhesive to preserve theoverall thermal conductivity. The adhesive layer 310 can be used toaffix the heat sink 220 to the electronic component 200. In someembodiments, the sheet 300 includes a second adhesive layer, the twolayers facilitating the adherence of the heat sink 220 to the electroniccomponent 200. In some embodiments, the adhesive layer 310 is formulatedusing a pressure-sensitive, thermally-conducting adhesive. Thepressure-sensitive adhesive (PSA) may be generally based on compoundsincluding acrylic, silicone, rubber, and combinations thereof. Thethermal conductivity is enhanced, for example, by the inclusion ofceramic powder.

In an alternative embodiment, referring now to FIG. 3B, the thermal EMIshield may be formed as a tape 320. The tape 320, for example, can bestored on a roll 330, similar in form to a conventional roll ofadhesive-backed tape. The tape 320 generally exhibits construction andcomposition features similar to those already described in relation tothe sheet 300 of FIG. 3A. Similar to the sheet 300, the tape 320includes a second width (W″) and a second thickness (T″). In general,the length for a tape roll embodiment is arbitrary, because the lengthof the tape 320 is substantially longer than any individual application.Accordingly, lengths of tape 320 suitable for intended applications canbe separated (for example, “cut”) from the roll 330. Again, similar tothe previously described sheet 300, the tape 320 can include a firstadhesive layer 340. The tape 320 can also include a second adhesivelayer, similar to two-sided fastening tape.

Referring now to FIG. 4, an alternative embodiment of a thermal EMIshield 100 configured as a sheet 400 is illustrated. In this embodiment,desired application shapes, such as a rectangle 410′ and an ellipse 410″(generally 410) can be die-cut from the sheet 400, thereby yieldingthermal EMI absorbers 100 of any desired two-dimensional shape.Accordingly, the sheet 400 can be die-cut to produce the desiredoutlines of the application shapes 410. Alternatively, the desiredoutlines of the application shapes 410 can be custom cut from the blanksheet 300 shown in FIG. 3A.

In yet another embodiment, the thermal EMI shield material may bepreformed in any desired shape. Referring now to FIG. 5, a preformedshield 500 in a non-planar application is illustrated. The thermal EMIshield may be molded or extruded in any desired shape, such as therectangular trough shown, a cylindrical trough, and semi-circulartrough. Such non-planar thermal EMI shields 500 can be used inconnection with non-planar electrical components 200, such ascylindrical devices or components (for example, “cans”).

Referring to FIG. 6, an embodiment of a liquid thermal EMI shield 600 isillustrated. In general, a vessel 610 is shown holding a liquid thermalEMI shield solution 620. A portion of the solution 620 “A” isillustrated in greater detail in an insert labeled “Detail View A.” Thedetail view illustrates that the solution 620 includes EMI absorberparticles 630 and thermal conductor particles 640, each suspended withina liquid matrix 650. Generally, the attributes of the particles 630,640are similar to the attributes of the corresponding particles 110,120described in relation to FIG. 1. Similar to the matrix described inrelation to FIG. 1, the liquid matrix 650 is substantially transparentto electromagnetic radiation. The liquid matrix 650 can be formed as aliquid that may be painted onto an applicable surface to be treated.Alternatively, the liquid matrix 650 can be formed as a gel, such asgrease, or as a paste or pour-in-place compound. In some embodiments,the liquid thermal EMI shield 600 can be applied to the intended surfaceby painting, spraying, or other suitable method. The matrix material mayalso be a liquid selected from the group consisting of silicones,epoxies, polyester resins and combinations thereof.

In one embodiment, the matrix 130 illustrated in FIG. 1 is a suitablyselected phase-change material having properties of both a solid and aliquid. At ambient room temperatures, the phase-change material behavesas a solid offering ease of handling and storage. The phase-changematerial, however, exhibits a reflow temperature at or below theequipment operating temperature thereby enabling a “wetting action.” Thematrix 130 reflows allowing the EMI-absorbing particles 110 and thethermally conductive particles 120 of the composite material 100 to flowinto any gaps, such as those caused by surface imperfections.

Referring to FIG. 7, a close-up detail of a cross-sectional view of anelectronic component 700, a heat sink 710, and a thermally conductingEMI shield 720 is illustrated. Also shown are the surface imperfections730 of each or both of the component 700 and heat sink 710. The surfaceimperfections 730 are portrayed in an exaggerated manner for the purposeof illustration. With an ability to flow into surface imperfections 730,a matrix 650 formulated as a liquid, or phase-change material removesair gaps, thereby minimizing the thermal impedance between the device700 and an associated heat sink 710. The overall effect of removing airgaps reduces the thermal impedance between the electrical component 700and the heat sink 710, leading to improved heat transfer efficiency. Thematrix material may be a mixture of a paraffin wax having a meltingpoint of approximately 51° C. and a 28% ethylene-vinyl acetate copolymerhaving a melting point of approximately 74° C. For example, a mixture ofninety-five parts by weight of the paraffin wax and five parts by weightof the ethylene-vinyl acetate copolymer may be used. Alternatively, amixture of twenty-five parts by weight of the paraffin wax and six partsby weight of the ethylene-vinyl acetate copolymer may be used.Alternatively still, the matrix material may be a synthetic wax having amelting point of approximately 100° C. and a molecular weight ofapproximately 1000. Such a wax is of a type known as a Fischer-Tropschwax.

Referring to FIG. 8, a flow diagram is illustrated depicting a processof preparing a thermally-conductive EMI absorber 100, such as theembodiments illustrated in either FIG. 1 or FIG. 6. EMI absorberparticles 110,630 are provided at step 800. Thermally conductiveparticles 120,640 are also provided at step 810. The EMI absorberparticles 110,630 and thermally conducting particles 120,640 arecombined and suspended within either a solid matrix material 130, or aliquid matrix material 650. Once prepared, the composite thermal EMIshield 100,600 is applied between an electronic component 200,700 and aheat sink 220,710 at step 830.

Having shown exemplary and preferred embodiments, one skilled in the artwill realize that many variations are possible within the scope andspirit of the claimed invention. It is therefore the intention to limitthe invention only by the scope of the claims, including all variantsand equivalents.

APPENDIX A

Test Report

Scope:

This report summarizes the thermal conductivity testing of multipleelectromagnetic-energy-absorbing materials including a thermallyconductive filler to also provide good thermal conductivity.

Part Description:

Three test samples were prepared and tested for thermal performance.Each of the samples consisted of iron (Fe)-filled elastomeric materialsformulated to absorb electromagnetic surface waves. Some specificdetails for the test samples are listed below in Table 1.

TABLE 1 Test Samples Sample No. Test Sample Description 1 50% Fe byvolume in isoprene, test slab thickness of 30, 60, 90 and 125 mils. 241.5% Fe by volume in silicone, test slab thickness of 20, 30, 60 and100 mils. 3 40% Fe plus 20% aluminum nitride (AlN) by volume insilicone, test slab thickness of 30, 60, 90 and 120 mils.Test Procedure:

Thermal resistance testing was conducted in accordance with in internaltest procedure and in accordance with ASTM specification D5470. The testsamples were first die-cut into 1-inch-diameter circles to match thesize of the thermal impedance probes. All of the thermal resistancemeasurements were made at 50° C., and 100 psi.

The test fixture 900 is shown in FIG. 9. The test sample 910 is placedbetween two polished metal plates 920,930 that are stacked within thetest assembly 900 as shown in FIG. 9. The heat is input from the heaterplate 940, which is protected from heat loss in all directions otherthan the testing direction by applying the same temperature to a guardheater 950 that is located above and around the heater plate 940. Anupper meter block 920 is located directly below the heater 940 and isfollowed by the test sample 910 find then a lower meter block 930. Heatis drawn out from the bottom of the test stack with a water-cooledchiller plate 960. Thermocouples 970 embedded in the meter blocks920,930 are used to extrapolate the surface temperature on each side ofthe test sample 910. This is done using a SRM 1462 reference materialthat has a thermal conductivity much greater than that of the testsample.

During the test the sample is compressed at a constant pressure using apneumatic cylinder. The stack is then permitted to reach a steady stateat which point the thermal resistance of the sample is calculated. Oncethe thermal resistance of several thickness of material (nominally five)is measured and plotted the thermal conductivity is calculated as theinverse of the slope of the least squares best fit line through thisdata.

Test Results:

The thermal conductivity of the three absorbing test samples is shown inTable 2. The two standard absorbing materials, Sample No. 1 and SampleNo. 2, have very similar thermal conductivities (approximately 1.0Watts/m−° C.), whereas the third absorber material, Sample No. 3, has asubstantially higher thermal conductivity (approximately 1.5 Watts/m−°C.).

TABLE 2 Thermal Conductivity Thermal Conductivity Standard Test Sample(Watts/m-° C.) Deviation Sample No. 1 0.986 0.0632 Sample No. 2 1.0220.0959 Sample No. 3 1.511 0.0637

APPENDIX B NITRILE RUBBER (40%) Frequency (GHz) μ_(r) μ_(i) ∈_(r) ∈_(i)0.915 4 −1.77 12.277 −0.251 1.15 4 −1.77 12.277 −0.251 2 3.4 −1.7412.277 −0.251 2.245 3.29 −1.735 12.277 −0.251 3 2.95 −1.72 12.277 −0.2514 2.58 −1.67 12.277 −0.251 5 2.219 −1.624 12.277 −0.251 6 2.05 −1.5812.277 −0.251 7 1.88 −1.55 12.277 −0.251 8 1.65 −1.52 12.277 −0.251 91.5 −1.48 12.277 −0.251 9.5 1.45 −1.43 12.277 −0.251 10 1.39 −1.4 12.277−0.251 11 1.34 −1.36 12.277 −0.251 12 1.27 −1.32 12.277 −0.251 13 1.201−1.273 12.277 −0.251 14 1.18 −1.24 12.277 −0.251 15 1.14 −1.21 12.277−0.251 15.5 1.1 −1.18 12.277 −0.251 16 1.057 −1.147 12.277 −0.251 171.04 −1.125 12.277 −0.251 18 1.03 −1.1 12.277 −0.251 20 0.854 −0.95512.277 −0.251 25 0.68 −0.74 12.277 −0.251 30 0.6 −0.54 12.277 −0.251 350.533 −0.34 12.277 −0.251 40 0.461 −0.165 12.277 −0.251

1. A thermally conductive composite material for reducingelectromagnetic emissions generated by an electronic device, saidthermally conductive composite material comprising: a thermallyconductive material in particulate form; and anelectromagnetic-energy-absorptive material in particulate form, saidthermally conductive material and said electromagnetic-energy-absorptivematerial being suspended within a polymeric base material, saidpolymeric base material being substantially transparent toelectromagnetic energy, said polymeric base material comprising aphase-change material and up to 19.35% by weight of ethylene-vinylacetate, the phase-change material comprising a paraffin wax or asynthetic wax, wherein the phase-change material has a reflowtemperature that allows the thermally conductive material in particulateform that is suspended within the polymeric base material to flow intogaps and thereby at least reduce thermal impedance, wherein saidthermally conductive composite material is configured such that whenplaced between an electronic device and a proximate structure, saidthermally conductive material is operable for facilitating transfer ofthermal energy from said electronic device and saidelectromagnetic-energy-absorptive material is operable for reducingelectromagnetic emissions generated by the device, and wherein theelectromagnetic-energy-absorptive material includes carbonyl iron.
 2. Athermally conductive composite material as claimed in claim 1 wherein atleast one of said thermally conductive material and saidelectromagnetic-energy-absorptive material comprises particles in theform of granules having a spheroid shape.
 3. A thermally conductivecomposite material as claimed in claim 2 wherein the thermallyconductive material comprises microspheres.
 4. A thermally conductivecomposite material as claimed in claim 1 wherein said thermallyconductive material is selected from the group consisting of aluminumnitride, boron nitride, iron, metallic oxides and combinations thereof.5. A thermally conductive composite material as claimed in claim 1wherein said thermally conductive material is a ceramic material.
 6. Athermally conducting composite material as claimed in claim 1 whereinsaid polymeric base material has a relative dielectric constant of lessthan approximately 4 and a loss tangent of less than approximately 0.1.7. A thermally conductive composite material as claimed in claim 1wherein said polymeric base material is selected from the groupconsisting of elastomers, natural rubbers, synthetic rubbers, PDP, EPDMrubber, and combinations thereof.
 8. A thermally conductive compositematerial as claimed in claim 1 wherein said polymeric base material isselected from the group consisting of silicone, fluorosilicone,isoprene, nitrile, chlorosulfonated polyethylene, neoprene,fluoroelastomer, urethane, thermoplastics, thermoplastic elastomer(TPE), polyamide TPE, thermoplastic polyurethane (TPU), and combinationsthereof.
 9. A thermally conductive composite material as claimed inclaim 1 wherein said polymeric base material is a solid materialselected from the group consisting of thermoplastic and thermosettingmaterials.
 10. A thermally conductive composite material as claimed inclaim 1 wherein said polymeric base material is a liquid.
 11. Athermally conductive composite material as claimed in claim 10 whereinsaid liquid is selected from the group consisting of silicones, epoxies,polyester resins, and combinations thereof.
 12. A thermally conductivecomposite material as claimed in claim 1 wherein said polymeric basematerial comprises a phase-change material configured to exist in asolid phase at ambient room temperature and transition to a liquid phaseat a reflow temperature.
 13. A thermally conductive composite materialas claimed in claim 1 wherein said polymeric base material comprises amixture of a paraffin wax and an ethylene-vinyl acetate copolymer.
 14. Athermally conductive composite material as claimed in claim 1 whereinsaid polymeric base material comprises a synthetic wax having a meltingpoint of approximately 100° C. and a molecular weight of approximately1000.
 15. A thermally conductive composite material as claimed in claim1 wherein said electromagnetic-energy-absorptive material has a relativemagnetic permeability greater than about 3.0 at approximately 1.0 GHzand greater than about 1.5 at 10GHz.
 16. A thermally conductivecomposite material as claimed in claim 1 wherein said composite materialis in the form of a sheet having a thickness greater than approximately0.01 inches.
 17. A thermally conductive composite material as claimed inclaim 1 wherein said composite material is in the form of a sheet havinga thickness less than approximately 0.18 inches.
 18. A thermallyconductive composite material as claimed in claim 1 wherein saidcomposite material is in the form of a sheet, and further comprises anadhesive on at least one side of said sheet.
 19. A thermally conductivecomposite material as claimed in claim 18 wherein said adhesive is athermoconductive adhesive.
 20. A thermally conductive composite materialas claimed in claim 18 wherein said adhesive is a pressure-sensitive,thermally conductive adhesive.
 21. A thermally conductive compositematerial as claimed in claim 18 wherein said adhesive is based oncompounds selected from the group consisting of acrylics, silicones,rubbers and combinations thereof.
 22. A thermally conductive compositematerial as claimed in claim 18 wherein said adhesive further comprisesa ceramic powder.
 23. A thermally conductive composite material asclaimed in claim 1 wherein the electromagnetic-energy-absorptivematerial includes generally ellipsoidal carbonyl iron granules.
 24. Athermally conductive composite material as claimed in claim 1 whereinthe electromagnetic-energy-absorptive material is entirely carbonyliron.
 25. A thermally conductive composite material as claimed in claim1 wherein: the electromagnetic-energy-absorptive material exhibitsbetter thermal conductivity than air; and the thermally conductivematerial exhibits greater thermal conductivity than theelectromagnetic-energy-absorptive material, the thermally conductivematerial having a thermal impedance value substantially less than thatof air.
 26. A thermally conductive composite material as claimed inclaim 1 wherein the composite material includes about 60 percent byvolume of the thermally conductive material and theelectromagnetic-energy-absorptive material.
 27. A thermally conductivecomposite material as claimed in claim 1 wherein: the thermallyconductive material in particulate form comprises granules spaced-apartfrom each other; the electromagnetic-energy-absorptive material inparticulate form comprises granules spaced apart from each other andspaced-apart from the granules of the thermally conductive material; andthe composite material is electrically non-conductive.
 28. A thermallyconductive composite material as claimed in claim 1 wherein saidpolymeric base material comprises a mixture of 25 parts by weight of aparaffin wax and 6 parts by weight of an ethylene-vinyl acetatecopolymer.
 29. A thermally conductive composite material as claimed inclaim 1 wherein said polymeric base material comprises a mixture of 95parts by weight of a paraffin wax and 5 parts by weight of anethylene-vinyl acetate copolymer.
 30. A thermally conductive compositematerial as claimed in claim 1 wherein said polymeric base materialcomprises a mixture of a paraffin wax in an amount of about 80.65% byweight and an ethylene-vinyl acetate copolymer in an amount of about19.35% by weight.
 31. A thermally conductive composite material asclaimed in claim 1 wherein said polymeric base material comprises amixture of a paraffin wax in an amount of about 95% by weight and anethylene-vinyl acetate copolymer in an amount of about 5% by weight. 32.A thermally conductive composite material as claimed in claim 1 whereinsaid polymeric base material comprises a mixture of a paraffin wax in anamount of between about 80.65% and about 95% by weight and anethylene-vinyl acetate copolymer in an amount of between about 5% andabout 19.35% by weight.
 33. A thermally conductive composite material asclaimed in claim 1 wherein said polymeric base material comprises amixture of paraffin wax having a melting point of approximately 51degrees Celsius and a 28% ethylene-vinyl acetate copolymer having amelting point of approximately 74 degrees Celsius.
 34. An electroniccomponent comprising an integrated circuit, a heat sink, and thecomposite material of claim
 1. 35. A method of reducing electromagneticemissions produced by a device comprising: combining a thermallyconductive material in particulate form with anelectromagnetic-energy-absorptive material in particulate form, theelectromagnetic-energy-absorptive material including carbonyl iron;suspending the combined thermally conductive material andelectromagnetic-energy-absorptive material in a polymeric base materialcomprising a phase-change material and up to 19.35% by weight ofethylene-vinyl acetate, the phase-change material comprising a paraffinwax or a synthetic wax; and placing the combined thermally conductivematerial and electromagnetic-energy-absorptive material suspended in thepolymeric base material between said device and a proximate structure,wherein the phase-change material has a reflow temperature that allowsthe thermally conductive material in particulate form suspended withinthe polymeric base material to flow into gaps and thereby at leastreduce thermal impedance between the device and the proximate structure.36. The method of claim 35 wherein the proximate structure comprises aheat sink.
 37. The method of claim 35 wherein said device comprises anintegrated circuit.
 38. The method of claim 35 wherein: the combinedthermally conductive material and electromagnetic-energy-absorptivematerial suspended in the polymeric base comprise a liquid solution; andplacing comprises applying the liquid solution onto a surface of atleast one of the device and the proximate structure having one or moresurface imperfections, and allowing the liquid solution to flow into theone or more surface imperfections.
 39. The method of claim 35 wherein:the combined thermally conductive material andelectromagnetic-energy-absorptive material suspended in the polymericbase comprise a liquid solution; and placing comprises spraying orpainting the liquid solution onto a surface of at least one of thedevice and the proximate structure.
 40. The method of claim 35 whereinsaid polymeric base material comprises a mixture of 25 parts by weightof a paraffin wax and 6 parts by weight of an ethylene-vinyl acetatecopolymer.
 41. The method of claim 35 wherein said polymeric basematerial comprises a mixture of 95 parts by weight of a paraffin wax and5 parts by weight of an ethylene-vinyl acetate copolymer.
 42. Athermally conductive composite material as claimed in claim 1 wherein:the composite material is in the form of a sheet having a thickness ofabout 0.125 inch and exhibits an attenuation of at least about 5 dB in afrequency range from about 5 GHz up to at least about 18 GHz; or thecomposite material is in the form of a sheet having a thickness of about0.02 inch and exhibits an attenuation of at least about 3 dB for afrequency range extending upward from about 10 GHz; or the compositematerial is in the form of a sheet having a thickness of about 0.04 inchand exhibits an attenuation of at least about 10 dB in a frequency rangefrom about 9 GHz up to at least about 15 GHz and an attenuation of atleast about 6 dB in a frequency range extending upward from about 15GHz; or the composite material is in the form of a sheet having athickness of about 0.060 inch and exhibits an attenuation of at leastabout 5 dB in a frequency range extending upward from about 4 GHz,having a greater attenuation of at least about 10 dB in a frequencyrange from about 6 GHz up to at least about 10 GHz.
 43. A thermallyconductive composite material as claimed in claim 1 wherein saidpolymeric base material comprises a mixture of a paraffin wax and anethylene-vinyl acetate copolymer, including an amount of the paraffinwax within a range of from about 25 parts by weight paraffin wax to 6parts by weight ethylene-vinyl acetate copolymer, up to about 95 partsby weight paraffin wax and 5 parts by weight of ethylene-vinyl acetatecopolymer.